Evgeniy Schukin VII.4

The textbook outlines the main sections of modern colloid chemistry - the science of the dispersed state of matter: the doctrine of surface phenomena, the properties of adsorption layers, the preparation and properties of dispersed systems, their stability and stabilization, structure formation in dispersed systems, their theoretical and experimental foundations and principles of practical application are given . Such fundamental problems as the mechanisms of action of surfactants, lyophilicity and spontaneous dispersion, physical and chemical mechanics are presented.

Corresponds to the Federal State Educational Standard of Higher Professional Education of the third generation.
For students of universities and chemical-technological universities.

		6
Introduction		8
CHAPTER I. Interface and capillary phenomena		15
I.1. Thermodynamic characteristics of the surface in one-component systems		15
I.2. Surface energy and intermolecular interactions in one-component systems		25
I. 3. Interfaces between condensed phases in two-component systems		37
I.4. Wetting and spreading		43
I.5. Effect of Surface Curvature on Phase Equilibrium		55
I.5.I. Laplace's law.		55
I.5.2. Thomson (Kelvin) equation		61
I. 6. Methods for determining the surface tension of liquids and specific free surface energy of solids		63
Chapter II. adsorption phenomena. Structure and properties of adsorption layers at the liquid-gas interface		72
II. 1. Fundamentals of adsorption thermodynamics. Gibbs equation		73
II.2. Adsorption of soluble surfactants		86
II.3. Adsorption layers of insoluble surfactants		96
II. 4. Classification of surfactants and modern range of synthetic surfactants		111
Chapter III. Adsorption phenomena on the interfaces of the condensed phases. Electrosurface phenomena		121
III. 1. Adsorption of surfactants on interfaces between condensed phases		121
Sh.2. The use of surfactants to control wetting processes and selective wetting		132
III.3. Ion adsorption; structure of the electrical double layer		139
III.4. Ion exchange		154
III.5. electrocapillary phenomena.		159
Chapter IV. Transfer processes in dispersed systems. Electrokinetic Phenomena		162
IV. 1. General consideration of transfer processes in dispersed systems		162
IV.2. General ideas about the nature of electrokinetic phenomena		168
IV. 3. Transfer processes in free-disperse systems		174
IV.4. Features of transfer processes in coherently dispersed systems (porous diaphragms and membranes)		182
TV 5 Influence of electolites on electrokinetic phenomena		190
Chapter V. Molecular-Kinetic and Optical Properties of Dispersed Systems. Analysis of variance		195
V.I. Sedimentation and diffusion in dispersed systems		195
V.2. Brownian motion and fluctuations in the concentration of particles of the dispersed phase		201
V.3. Scattering of light by small particles (according to Rayleigh)		208
V.4. Optical properties of dispersed systems with increasing particle size		213
V.5. ANOVA METHODS		218
V.5.I. Sedimentation analysis		222
V.5.2. Use of centrifuges and ultracentrifuges in analysis of variance		225
V.5.3. Nephelometry. ultramicroscopy		228
V.5.4. Scattering of light by concentration fluctuations		229
Chapter VI. Formation of lyophilic and lyophobic disperse systems		233
VI.1 Lyophilic and lyophobic dispersion systems		234
VI.2. Micellization in Surfactant Solutions		242
VI.2.1. Thermodynamics of micellization		245
V1.2.2. Concentrated dispersions of micelle-forming surfactants		251
VI.2.3. Micellization in non-aqueous media		253
VI.3. Solubilization in solutions of micelle-forming surfactants, formation of microemulsions		255
VI.4. critical emulsions. Lyophilic colloidal systems in dispersions of macromolecular compounds		262
VI.5. Condensation formation of lyophobic disperse systems		267
VI.5.1. Thermodynamic foundations of homogeneous nucleation (according to Gibbs - Volmer)		267
VI.5.2. Heterogeneous formation of a new phase		273
VI.5.3. Kinetics of the emergence of nuclei of a new phase in a metastable system		277
VI.5.4. Growth rate of new phase particles		280
VI.6 Obtaining lyophobic disperse systems		284
Chapter VII. General causes of destruction and relative stability of polyphobic dispersed systems		291
VII. 1. Sedimentation and aggregation stability of dispersed systems. Role of thermal motion		292
VII.2. Thin films		297
VII.3. Molecular interactions in disperse systems		303
VII.4. Factors of stabilization of disperse systems		311
VII.5. Electrostatic component of the disjoining pressure and its role in the stability of dispersed systems. Fundamentals of the DLVO theory		316
VII.6. Structural-mechanical barrier		325
VII.7. Kinetics of coagulation		328
VII.8. The effect of isothermal distillation on the reduction of fineness		334
Chapter VIII. Features of the structure, stability and destruction of disperse systems of various nature		339
VIII. 1. Aerosols		339
V1II.2. Foams and foam films		347
VIII.3. Emulsions and emulsion films		354
VIII.4. Suspensions and sols		364
V1II.5. Coagulation of hydrophobic sols with electrolytes		368
VIII.6. washing action. Microencapsulation		372
VIII.7. Systems with a solid dispersion medium		375
Chapter IX. Fundamentals of physical and chemical mechanics		377
IX.1. Methods for describing mechanical properties. Fundamentals of rheology		379
IX.2. Structure formation in disperse systems		388
IX.3. Rheological properties of disperse systems		401
IX.4. Physical and chemical phenomena in the processes of deformation and destruction of solids. Rebinder effect		410
1X.4.1. Influence of the chemical nature of a solid body and a medium on the manifestation of an adsorption decrease in strength		412
IX.4.2. The role of the real structure of a solid and external conditions in the manifestation of the effects of adsorption the influence of the medium on the mechanical properties of solids		418
IX.4.3. Applications of the Rebinder Effect		423
Conclusion		427
Literature		433
Subject index		434

Dedicated to blessed memory
our teacher
Peter Alexandrovich Rebinder

Foreword

The book reflects the main sections of modern colloid chemistry - a large independent field of chemical science that studies the dispersed state of matter and surface phenomena in dispersed systems. It summarizes many years of experience in pedagogical, methodological and scientific work of the staff of the Department of Colloidal Chemistry, Faculty of Chemistry, Moscow State University. M. V. Lomonosov.

The development of colloid chemistry and its teaching at Moscow University is inextricably linked with the activities of Academician Petr Alexandrovich Rebinder (1898-1972), who for 30 years headed the Department of Colloidal Chemistry and laid the foundations for the modern course of this science. In 1973-1994 the department was headed by Academician of the Russian Academy of Education E. D. Shchukin, whose lecture notes were the source material for this book, in 1994-2005. - Professor B. D. Summ, and since 2006 the department has been headed by Corresponding Member of the Russian Academy of Sciences V. G. Kulichikhin.

In the fourth and fifth editions of the textbook, the necessary adjustments and revisions were made compared to the previous substantially revised edition of 2004, taking into account the entire 20-year experience of using the textbook for teaching colloidal chemistry at Moscow State University and other universities of the CIS and abroad. The first edition was translated into Spanish (1988 "Mir") and Czech (1990 "Akademia" Praha) languages, the second - into English (2001 Elsevier).

The authors tried to combine the depth and rigor of the presentation of the main material with its sufficient accessibility for students with different levels of training. Material of an increased degree of complexity, containing details of the conclusions, and material intended for a more in-depth study of the subject, are given by petite.

The proposed textbook is designed primarily for students of chemical faculties of universities. It can serve as a manual for students of other faculties of universities and for students of other universities in which colloid chemistry is studied as an independent subject. The book can also be used by a wide range of scientists and graduate students, engineers and technologists employed in various fields of science and production related to the use of dispersed systems and surface phenomena.

The authors tried to take into account as much as possible the wishes expressed by the teachers of the Department of Colloid Chemistry, the head of the department, the leadership of the faculty, colleagues in other educational institutions and research centers, as well as participants in the session of the Council on Colloid Chemistry and Physical and Chemical Mechanics of the Russian Academy of Sciences, dedicated to the problems of colloidal chemistry education (Moscow , 2001). Many specific recommendations were made by V. N. Izmailova, N. M. Zadymova, N. I. Ivanova, S. M. Levacheva, L. I. Lopatina, V. N. Matveenko, V. V. , A. V. Sineva, Z. N. Skvortsova, O. A. Soboleva, B. D. Summ, V. Yu. Traskin. Significant remarks were made in the reviews of the teams of teachers of the departments of colloidal chemistry of St. Petersburg University (Head of the Department, Academician A.I. D. I. Mendeleev (Head of the Department, Prof. V. V. Nazarov). These advices and wishes were met with sincere gratitude.

With heartfelt gratitude and the most tender feelings, I turn to my dear students, friends, assistants - as if they were with me now - to Sasha Pertsov and Lenochka Amelina.

Country:

Russia

Scientific area: Place of work:

Johns Hopkins University

Academic degree: Alma mater: Scientific adviser: Known as:

Head of the Department of Colloidal Chemistry, Moscow State University

Awards and prizes

Evgeny Dmitrievich Schukin(born May 30, 1928 in Moscow) - Soviet scientist in the field of physical chemistry, Doctor of Physical and Mathematical Sciences, professor, Lenin Prize laureate, academician.

Biography

He won first place at the All-Moscow Mathematical Olympiad in 1945, and graduated from school the same year. He, the first in the USSR, was awarded a gold medal "For excellent success and exemplary behavior" and a matriculation certificate No. 000001. He might not have received a medal due to his background, if not for the headmaster I. K. Novikov.

Scientific activity

E. D. Shchukin carried out experimental and theoretical research in the field of physical and colloidal chemistry of disperse systems, surface phenomena and surfactants. He studied the mechanisms of action of surfactants at various interfaces, obtaining and regulating the stability of disperse systems (sols, gels, emulsions, foams, aerosols). Phenomena such as adhesion, sintering, hydration hardening, sol-gel transition, embrittlement under the action of liquid metals, wear, lubricating action, etc., as well as their molecular mechanisms, have been studied. The doctrine of the interaction of particles and structure formation in disperse systems has been created, colloid-chemical methods have been developed to protect the environment. Academician E. D. Schukin is interested in the physical chemistry of surface phenomena in solids, the theory of dislocations, the influence of a surface-active medium on the mechanical properties of materials, especially in thin surface layers. In addition, practical research applications have been made: increasing the strength and durability of catalysts, mineral binders and ceramics, processing of highly hard materials, drilling of hard rocks.

E. D. Shchukin continued and developed the work of P. A. Rebinder in the field of stability and spontaneous dispersion, studied the molecular mechanisms of the action of surfactants, built a physicochemical theory of structure formation and strength of dispersed structures. He was the first to carry out computer simulation of the "Rebinder effect".

E. D. Shchukin created the general course "Colloid Chemistry", a special course "Physical-Chemical Mechanics of Disperse Systems and Materials", was the supervisor of more than 40 defended candidate's theses.

In the field of pedagogical research, the works of E. D. Shchukin are devoted to the importance of interdisciplinary areas of science and their technical applications in the knowledge system and the development of methods for their reflection in subjects of the natural and mathematical cycle.

E. D. Shchukin in different years was a member of the specialized councils of the Faculty of Chemistry of Moscow State University, the Institute of Physical Chemistry of the Russian Academy of Sciences, the Institute of Metallurgy of the Academy of Sciences of the USSR, the Institute of Content and Teaching Methods of the Russian Academy of Education, a member of the National Committee of Russian Chemists, the Higher Attestation Commission of the USSR, a member of the editorial boards of journals: “Colloid Journal ”, “Friction and wear”, “Physics at school”, “Physical and chemical mechanics of materials”, “Physics and chemistry of materials processing”. Currently he is a member of the editorial boards of the international scientific journals "Journal of Materials Science", "Journal of Dispersion Science and Technology", "Colloids and Surfaces", "Colloid & Interface Science", "Advances in the Mechanics and Physics of Surfaces", "Zeitschrift für Physikalische Chemie".

Awards and titles

On March 4, 1965, E. D. Schukin was elected a corresponding member of the APN of the RSFSR, from February 2, 1968 - a corresponding member of the APN of the USSR. On May 23, 1985, he was elected an academician of the Academy of Sciences of the USSR, from April 7, 1993 - a full member of the Russian Academy of Education, department of general secondary education. E. D. Shchukin is an academician of the Russian Academy of Engineering (since 1990), the Russian Academy of Natural Sciences (since 1990), the US National Academy of Engineering (since 1984), the Royal Swedish Academy of Engineering Sciences (since 1988).

In 1995 he was awarded the title of honorary professor of Moscow State University. In 1972 he was awarded the Lomonosov Prize of Moscow State University, in 1988 - the Lenin Prize for work in the field of physical and chemical mechanics, in 1988 - the P. A. Rebinder Prize. In 1986 he was awarded the Order of the Badge of Honor.

Main scientific works

In total, E. D. Shchukin received 40 certificates for inventions and 2 diplomas for scientific discoveries, published more than 600 scientific papers, 5 books, including:

Likhtman V. I., Shchukin E. D., Rebinder P. A. Physical and chemical mechanics of metals. M.: AN SSSR, 1962.
Pertsev N.V., Traskin V.Yu., Skvortsova 3.N., Shchukin E.D. Destruction of ionic crystals in the presence of solutions and molten salts. "Physical chemistry of surface phenomena in melts" //ed. V. N. EVREMENKO. M.: 1971, - 295 p.
Shchukin E. D., Bessonov A. I., Paranskiy S. A. Mechanical testing of catalysts and sorbents. M.: Nauka, 1971. - 56 p.
Shchukin E. D. Connections between natural sciences and production in subjects of the natural and mathematical cycle, SP, 1975, No. 3
Schukin E. D. Physical and chemical mechanics. article in TSB.
Yaminsky VV, Pchelin VA, Amelina EA, Shchukin ED Coagulation contacts in dispersed systems. M.: Nauka, 1982. - 311 p.
Shchukin E. D., Bryukhanova L. S., Pertsov N. V. Influence of surface-active media on the mechanical properties of solids // In the yearbook “Physical Chemistry. Modern problems". Ed. acad. Ya. M. Kolotyrkina. - M.: Chemistry, 1983. p. 46-74.
Shchukin, E.D., Reciprocity of processes of rupture and rearrangement of interatomic bonds in the solid phase and medium molecules during catalysis, in: Proc. mechanism of catalysis. Part 2. - Novosibirsk: Nauka, 1984.
Shchukin E. D. Reserves for improving science education, SP, 1985, No. 2
Surface Water Films in Dispersed Structures, Ed. E. D. Schukina.-M.: Publishing House of Moscow State University, 1988.- 279c.-ISSN 5-211-O0112-5.
Colloidal Chemistry: A textbook for chemical specialties of universities and universities, 2nd ed. / E. D. Schukin, A. V. Pertsov, E. A. Amelina. - M.: Higher School, 1992. - 410 p.
Shishkovsky G. K., Shchukin E. D., Grinberg A. A. Installation for measuring the physicochemical parameters of disperse systems. Patent of the Russian Federation No. 2025709 dated May 5, 1991, class. G01N11.
Colloidal chemistry: A textbook for universities and chemical-technological universities / E. D. Schukin, A. V. Pertsov, E. A. Amelina. - 5th edition, revised - M .: Higher school, 2007. - 444 s: ill. - ISBN 978-5-06-005900-7
Shchukin, E.D., Pertsov, A.V., Amelina E.A. and Zelenev, A.S. Colloid and Surface Chemistry. 1st ed. Mobius D. and Miller R. Vol. 12. Amsterdam: Elsevier Science B.V. (2001)
Shchukin, E.D. "The role of contact interactions in the rheological behavior of a fibrous suspension". Colloid J. vol.63. (2001). pp. 855–858.
Shchukin, E.D. "Surfactants effects on the cohesive strength of particle contacts: measurements by the cohesive force apparatus". J. Colloid Interface Sci. vol.256. (2002). pp. 159–167.
Shchukin, E.D., Amelina, E.A "Surface modification and contact interaction of particles". J. Dispersion Sci. technology. vol.24. (2003). pp. 377–395.
Shchukin E.D. et al. Physico-chemical mechanics of particle-porous catalysts in active media //In Sat. "Physical and chemical mechanics of materials", v. 39, No. 3 (grass - worm). Lviv: Institute of Physics and Mechanics im. G. V. Karpenka, 2003.

Notes

Links

Eugene D. Shchukin - JHU Geography & Environmental Engineering Home | Johns Hopkins University | Whiting School of Engineering

Categories:

Personalities in alphabetical order
Scientists alphabetically
May 30
Born in 1928
Born in Moscow
Doctors of Physical and Mathematical Sciences
Graduates of the 110th school
Chemists of the USSR
Chemists of Russia
Chemists alphabetically
Graduates of the Faculty of Physics of Moscow State University
Moscow State University teachers
Academicians of the Russian Academy of Education
Active members of RIA
Laureates of the Lenin Prize
Laureates of the P. A. Rehbinder Prize

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Soviet scientist in the field of physical chemistry, doctor of physical and mathematical sciences, professor, laureate of the Lenin Prize, academician.

Born in Moscow in the family of a priest who was repressed in the 1930s and a teacher. In 1941-1943 - in evacuation in the Gorky region. In 1943-1944 he worked and studied, in 1945 he returned to the 10th grade of Moscow secondary school No. 110, having completed his exams as an external student.

He won first place at the All-Moscow Mathematical Olympiad in 1945, and graduated from school the same year. He, the first in the USSR, was awarded a gold medal "For excellent success and exemplary behavior" and a matriculation certificate No. 000001. He might not have received a medal because of his origin, if not for the director of the school, I. K. Novikov.

In 1950 he graduated with honors from the Faculty of Physics of Moscow State University with a degree in physics. In 1951-1956 he served as an officer in the Soviet Army. From September 1953 he taught radar at the military department of Moscow State University, then colloid chemistry. In 1973-1994 - Head of the Department of Colloidal Chemistry, Moscow State University. At the same time, since 1956, he worked at the Institute of Physical Chemistry of the USSR Academy of Sciences (now the A. N. Frumkin Institute of Physical Chemistry and Electrochemistry), since 1967 he was in charge of the laboratory of physical and chemical mechanics there.

In 1958 he defended his dissertation for the degree of candidate of physical and mathematical sciences (supervisors - P. A. Rebinder, V. N. Rozhansky) at the Institute of Physical Chemistry, in 1962 - at Moscow State University for the degree of Doctor of Physical and Mathematical Sciences.

Since 1994, E. D. Shchukin has been living in Baltimore, teaching courses in colloid chemistry and physical and chemical mechanics at the Johns Hopkins University. At the same time, he remains a professor at the Department of Colloidal Chemistry, Faculty of Chemistry, Moscow State University.

Scientific activity

By 1964, E. D. Shchukin created a theory of the strength of dispersed porous structures, developed methods for increasing the durability of industrial catalysts and sorbents. In 1969-1975, methods were developed for the use of surfactants to stabilize sols, emulsions and foams. In 1990, he discovered the catalytic acceleration of powder sintering.

ED Shchukin carried out experimental and theoretical research in the field of physical and colloidal chemistry of disperse systems, surface phenomena and surfactants. He studied the mechanisms of action of surfactants at various interfaces, obtaining and regulating the stability of disperse systems (sols, gels, emulsions, foams, aerosols). Phenomena such as adhesion, sintering, hydration hardening, sol-gel transition, embrittlement under the action of liquid metals, wear, lubricating action, etc., as well as their molecular mechanisms, have been studied. The doctrine of the interaction of particles and structure formation in disperse systems has been created, colloid-chemical methods have been developed to protect the environment. The area of interest of Academician E. D. Schukin includes the physical chemistry of surface phenomena in solids, the theory of dislocations, the effect of a surface-active medium on the mechanical properties of materials, especially in thin surface layers. In addition, practical applications of research have been carried out: increasing the strength and durability of catalysts, mineral binders and ceramics, processing highly hard materials, drilling hard rocks.

E. D. Shchukin continued and developed the work of P. A. Rebinder in the field of stability and spontaneous dispersion, studied the molecular mechanisms of the action of surfactants, built a physicochemical theory of structure formation and strength of disperse structures. He was the first to carry out computer simulation of the "Rebinder effect".

E. D. Shchukin created the general course "Colloid Chemistry", a special course "Physical-Chemical Mechanics of Dispersed Systems and Materials", was the supervisor of more than 40 PhD theses.

In the field of pedagogical research, the works of E. D. Shchukin are devoted to the significance of interdisciplinary areas of science and their technical applications in the knowledge system and the development of methods for their reflection in subjects of the natural and mathematical cycle.

E. D. Shchukin in different years was a member of the specialized councils of the Faculty of Chemistry of Moscow State University, the Institute of Physical Chemistry of the Russian Academy of Sciences, the Institute of Metallurgy of the Academy of Sciences of the USSR, the Institute of Content and Teaching Methods of the Russian Academy of Education, a member of the National Committee of Russian Chemists, the Higher Attestation Commission of the USSR, a member of the editorial boards of journals: “Colloid Journal ”, “Friction and wear”, “Physics at school”, “Physical and chemical mechanics of materials”, “Physics and chemistry of materials processing”. Currently he is a member of the editorial boards of international scientific journals "Journal of Materials Science", "Journal of Dispersion Science and Technology", "Colloids and Surfaces", "Colloid & Interface Science", "Advances in the Mechanics and Physics of Surfaces", Zeitschrift für Physikalische Chemie.

Awards and titles

In 1995 he was awarded the title of Honorary Professor of Moscow State University. In 1972 he was awarded the Lomonosov Prize of Moscow State University, in 1988 - the Lenin Prize for work in the field of physical and chemical mechanics, in 1988 - the P. A. Rebinder Prize. In 1986 he was awarded the Order of the Badge of Honor.

(1928-05-30 ) (91 years old) Academic title Professor
Academician APN USSR
Academician RAO

Evgeny Dmitrievich Schukin(born May 30, 1928, Moscow) - Soviet and Russian scientist in the field of physical chemistry, doctor of physical and mathematical sciences, professor, laureate of the Lenin Prize, academician of the Russian Academy of Education (1993).

Biography

He won first place at the All-Moscow Mathematical Olympiad in 1945, and graduated from school the same year. He, the first in the USSR, was awarded a gold medal "For excellent" successes and "exemplary" behavior "and a certificate of maturity No. 000001. He might not have received a medal because of his origin, if not for the director of the school I. K. Novikov.

E. D. Shchukin carried out experimental and theoretical research in the field of physical and colloidal chemistry of disperse systems, surface phenomena and surface-active substances. He studied the mechanisms of action of surfactants at various interfaces, obtaining and regulating the stability of disperse systems (sols, gels, emulsions, foams, aerosols). Phenomena such as adhesion, sintering, hydration hardening, sol-gel transition, embrittlement under the action of liquid metals, plasticization, wear, lubricating action, etc., as well as their molecular mechanisms, have been studied. The doctrine of the interaction of particles and structure formation in disperse systems has been created, colloid-chemical methods have been developed to protect the environment. Academician E. D. Schukin is interested in the physical chemistry of surface phenomena in solids, the theory of dislocations, the influence of a surface-active medium on the mechanical properties of materials, especially in thin surface layers. In addition, practical applications of research have been carried out: increasing the strength and durability of catalysts, mineral binders and ceramics, processing of highly hard materials, drilling of hard rocks.

E. D. Schukin continued and developed the work of P. A. Rebinder in a new field of science - physical and chemical mechanics, in the field of stability and spontaneous dispersion, studied the molecular mechanisms of action of surfactants, built a physical and chemical theory of structure formation and strength of dispersed structures . He was the first to carry out computer simulation of the “Rebinder effect”.

E. D. Shchukin created the general course "Colloid Chemistry", a special course "Physical-Chemical Mechanics of Disperse Systems and Materials" and textbooks in these disciplines, was the supervisor of more than 40 defended candidate's theses.

In the field of pedagogical research, the works of E. D. Shchukin are devoted to the analysis of the role of interdisciplinary areas of science and their technical applications in the knowledge system and the development of methods for their reflection in subjects of the natural and mathematical cycle.

E. D. Shchukin in different years was a member of the specialized councils of the Faculty of Chemistry of Moscow State University, the Institute of Physical Chemistry of the Russian Academy of Sciences, the Institute of Metallurgy of the Academy of Sciences of the USSR, the Institute of Content and Teaching Methods of the Russian Academy of Education, a member of the National Committee of Russian Chemists, the Higher Attestation Commission of the USSR, a member of the editorial boards of journals: “Colloid Journal ”, “Friction and wear”, “Physics at school”, “Physical and chemical mechanics of materials”, “Physics and chemistry of materials processing”, a member of the editorial boards of international scientific journals “Journal of Materials Science”, “Journal of Dispersion Science and Technology ”, “Colloids and Surfaces”, “Colloid & Interface Science”, “Advances in the Mechanics and Physics of Surfaces”, “Zeitschrift für Physikalische Chemie” .

Awards and titles

On March 4, 1965, E. D. Schukin was elected a corresponding member of the APN of the RSFSR, from February 2, 1968 - a corresponding member of the APN of the USSR. On May 23, 1985, he was elected an academician of the APS of the USSR, since April 7, 1993 - a full member of the Russian Academy of Education, department of general secondary education. E. D. Schukin - Academician of the Russian Academy of Engineering (since 1990), the Russian Academy of Natural Sciences (since 1990), the US National Academy of Engineering (since 1984), Swedish Academy of Engineering Sciences(since 1988).

In 1995 he was awarded the title of honorary professor of Moscow State University. In 1972 he was awarded the Lomonosov Prize of Moscow State University, in 1988 - the Lenin Prize for work in the field of physical and chemical mechanics, in 1998 - the P. A. Rebinder Prize of the Russian Academy of Sciences. In 1986 he was awarded the Order of the Badge of Honor, in 2008 - the Gold Medal of the Russian Academy of Education.

Main scientific works

In total, E. D. Shchukin received 40 certificates for inventions and 2 diplomas for scientific discoveries, published more than 800 scientific papers, 12 books, including:

IN AND. Lichtman, E.D. Schukin, P. A. Rebinder. PHYSICO-CHEMICAL MECHANICS OF METALS. Ed. Academy of Sciences of the USSR, Moscow 1962, 304 pp. Translation into English: Israel Program for Scientific Translation, Jerusalem, 1964, 243 p.
E.D. Schukin, Z.M. Zanozina, L.A. Kochanova, V.I. Lichtman, P.A. Rebinder. On the possibility of obtaining finely dispersed structures in alloys during hardening of their emulsions. DAN, І965, 160, No. 6, pp. 1355-1357.
E.D. Schukin. On some problems of the physicochemical theory of the strength of finely dispersed porous bodies - catalysts and sorbents. Kinetics and Catalysis, 1965, 6, No. 4, pp. 641-650.
P.A. Rehbinder, E.D. Shchukin. Surface phenomena in solids during deformation and fracture processes. Progress in Surface Science, Pergamon Press, Edit. S.G. Davison, Volume 3, Part 2, 1972, p.97-188.
E.D. Schukin. Physical and chemical bases of new methods of intensification of processing of solids. Bulletin of the Academy of Sciences of the USSR, І973, No. 11, pp. 30-40.
E.D. Schukin. Interdisciplinary connections and reflection of related fields of science in the disciplines of the natural-mathematical cycle. On Sat. Interdisciplinary connections in the process of teaching the basics of science in high school. Moscow, 1973, part II.
IN AND. Savenko, E.D. Schukin. Interaction between dislocations in helical beams of rosettes of etching figures. Crystallography, 1977, 22, No. 4, pp. 792-796.
E.D. Schukin, V.S. Yushchenko. Molecular dynamics of wetting. colloidal Zh., 1977, 39, No. 2, pp. 331-333.
E.D. Shchukin, V.S. Yushchenko. Molecular dynamics simulations of mechanical behavior. J. Material Science, 1981, 16, #2, p. 313-330.
E.D. Schukin, E.A. Amelina, V.V. Yaminsky. On the thermodynamic stability of dispersed systems. DAN, 1981, 258, No. 2, pp. 419-423.
E.D. Schukin, A.V. Pertsov, E.A. Amelina. COLLOID CHEMISTRY. 9 editions: Moscow, Ed. Moscow State University, 1982; HIGH SCHOOL, 1992, 2004, 2006, 2007; JURAIT, 2012, 2013, 444 pp. Translations: into Spanish, Editorial Mir Moscú, 1988 and Czech, Academia Praha, 1990.
V.V. Yaminsky, V.S. Yushchenko, E.A. Amelina, E.D. Shchukin. Cavity formation due to the contact between particles in a nonwetting liquid. J. Colloid and Interface Sci., 1983, 96, #2, p.301-306.
E.D. Schukin. V.S. Yushchenko, T.P. Ponomarev. Quantum-mechanical calculation of the elementary act of the influence of the medium on the strength of interatomic bonds. colloidal Zh., 1991, 53, No. 2, pp. 319-325.
E.D.Shchukin, E.A.Amelina, S.I.Kontorovich. Formation of contacts between particles and development of internal stresses during hydration processes. In: Materials Sciences of Concrete, Vol. 3, ed. by J.Skalny, The American Ceramic Soc., Westerwille, OH, 1992, p. 1-35.
E.D.Shchukin, S.I.Kontorovich, B.V.Romanovsky. Porous materials sintering under conditions of catalytic reactions. J. Materials Sci., 1993, 28, p.1937-1930.
E.D. Schukin. The development of the teachings of P.A. Rebinder on the factors of strong stabilization of disperse systems. colloidal Zh., 1997, 59, No. 2, pp. 270-284.
E.D.Shchukin, V.N.Izmailova, M.M.Krasnov, A.N.Gurov, A.I.Bessonov, G.N.Afanas’eva. Effect of the active media on the creep of the eye sclera. Colloid J., 1997, 59, p. 409-411.
Eugene D. Shchukin, Alexandr V. Pertsov, Elena A. Amelina, Andrei S. Zelenev. COLLOID AND SURFACE CHEMISTRY. 2001, ELSEVIER, Amsterdam, 745 p.
E.D.Shchukin. Surfactant effects on the cohesive strength of particle contacts: measurements by the cohesive force apparatus, J. Colloid Interface Science, 2002, 256, p.159-167.
E.D.Shchukin, Conditions of spontaneous dispersion and formation of thermodynamically stable colloid systems. J. of Dispersion Science and Technology, 2004, 25, p.875-893.
E.D.Shchukin, The influence of surface-active media on the mechanical properties of materials. Adv. Colloid Interface Sci., 2006, 123-126, p.33-47.
E.D.Shchukin, A.I.Bessonov, S.I.Kontorovich, Z.M.Polukarova, L.N.Sokolova, E.A.Amelina, L.N.Burenkova, B.V.Romanovsky, Effects of adsorption-active media on the mechanical properties of catalysts and adsorbents. Colloids and Surfaces, 2006, 282-283, p.287-297.
E.D.Shchukin, E.A.Amelina, A.M.Parfenova. Stability of fluorinated systems: Structure-mechanical barrier as a factor of strong stabilization. In: Highlights in Colloid Science, ed. by D. Platikanov and D. Exerova, Wiley-VCH, 2008, p.41-53.
Eugene Shchukin. Physical–Chemical Mechanics of Solid Surfaces. Encyclopedia of Surface and Colloid Science, Second Edition. Taylor and Francis, New York, 2012, p.1-23.
E.D.Shchukin. Nucleation and Crystal Growth in Cements. Encyclopedia of Colloid and Interface Science (ed. by T. Tadros), Springer-Verlag Berlin Heidelberg, 2013, p.783-817.
E.D. Schukin, V.I. Savenko, A.I. Malkin. LECTURES ON PHYSICAL AND CHEMICAL MECHANICS. Ed. NOBEL PRESS, Moscow, 2015, 678 pages.
Eugene D. Shchukin, Andrei S. Zelenev. PHYSICAL-CHEMICAL MECHANICS OF DISPERSE SYSTEMS AND MATERIALS. CRC Press, London - New York, 2016, 353 p.

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He won first place at the All-Moscow Mathematical Olympiad in 1945, and graduated from school the same year. He, the first in the USSR, was also awarded a matriculation certificate No. 000001. He might not have received a medal because of his origin, if not for the director of the school I. K. Novikov.

E. D. Shchukin carried out experimental and theoretical research in the field of physical and colloidal chemistry of disperse systems, surface phenomena and surfactants. He studied the mechanisms of action of surfactants at various interfaces, obtaining and regulating the stability of disperse systems (sols, gels, emulsions, foams, aerosols). Phenomena such as adhesion, sintering, hydration hardening, sol-gel transition, embrittlement under the action of liquid metals, plasticization, wear, lubricating action, etc., as well as their molecular mechanisms, have been studied. The doctrine of the interaction of particles and structure formation in disperse systems has been created, colloid-chemical methods have been developed to protect the environment. Academician E. D. Schukin is interested in the physical chemistry of surface phenomena in solids, the theory of dislocations, the influence of a surface-active medium on the mechanical properties of materials, especially in thin surface layers. In addition, practical research applications have been made: increasing the strength and durability of catalysts, mineral binders and ceramics, processing of highly hard materials, drilling of hard rocks.

E. D. Shchukin created the general course "Colloid Chemistry", a special course "Physical-Chemical Mechanics of Dispersed Systems and Materials" and textbooks in these disciplines, was the supervisor of more than 40 PhD theses.

E. D. Shchukin in different years was a member of the specialized councils of the Faculty of Chemistry of Moscow State University, the Institute of Physical Chemistry of the Russian Academy of Sciences, the Institute of Metallurgy of the Academy of Sciences of the USSR, the Institute of Content and Teaching Methods of the Russian Academy of Education, a member of the National Committee of Russian Chemists, the Higher Attestation Commission of the USSR, a member of the editorial boards of journals: “Colloid Journal ”, “Friction and wear”, “Physics at school”, “Physical and chemical mechanics of materials”, “Physics and chemistry of materials processing”, a member of the editorial boards of international scientific journals “Journal of Materials Science”, “Journal of Dispersion Science and Technology ”, “Colloids and Surfaces”, “Colloid & Interface Science”, “Advances in the Mechanics and Physics of Surfaces”, “Zeitschrift für Physikalische Chemie”

In 1995 he was awarded the title of honorary professor of Moscow State University. In 1972 he was awarded the Lomonosov Prize of Moscow State University, in 1988 - the Lenin Prize for work in the field of physical and chemical mechanics, in 1998 - the P. A. Rebinder Prize of the Russian Academy of Sciences. In 1986 he was awarded the Order of the Badge of Honor, in 2008 - the Gold Medal of the Russian Academy of Education.

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